Abstract:The 3 existing geothermal wells in Pingyin of Shandong Province are rich in physiotherapy mineral elements, with high physiotherapy value. Based on the hydrochemical and isotopic analysis data from previons works, the authors in this paper dissected hydrochemical characteristics, recharge source, formation age and water-rock interaction process of geothermal water, and estimated the temperature of heat storage, the proportion of cold water mixing proportions and the depth of hot water circulation. The results show that the hydrochemical types of geothermal water in the study area are all Cl·CO4-Na·Ca, and the source of water recharge is atmospheric precipitation, with the supply elevation of 274~277 m. The apparent age of 14C in geothermal water samples is 15.81~7.01 ka, indicating the mixed water is dominated by the ancient water. The occurrence of geothermal water was in different concealed base fault zones, but the solute component of geothermal water mainly comes from the dissolution of silicate minerals, meaning the similar hydrogeochemical process. The geothermal reservoir temperature calculated by chalcedony temperature is 46.2~54.4 ℃, while the geothermal reservoir temperature estimated by Si-enthalpy model is about 121~122 ℃, with cold water mixing proportion of about 0.76~0.88. The circulation depth of geothermal water is 1 428~5 139 m.
[1] 汪集旸,龚宇烈,马伟斌,等.我国发展地热能面临问题的分析及建议[C]//首届中国工程院/国家能源局能源论坛论文集.北京:化学工业出版社,2010:627-630. Wang J Y,Gong Y L,Ma W B,et al.Analysis and suggestions on the problems in the development of geothermal energy in Chi-na[C]//Proceedings of the First China Academy of Engineering/National Energy Administration Energy Forum.Beijing:Chemical Industry Press,2010:627-630. [2] 王奎峰,李文平,韩代成,等.山东省临清地热田地热水化学特征及热水起源研究[J].地质调查与研究,2014,37(3):230-236. Wang K F,Li W P,Han D C,et al.Hydrochemistry and origin of the Linqing geothermal field in Shandong Province[J].Geol Surv Res,2014,37(3):230-236. [3] 李振函,康凤新,刘国爱,等.济南地热温泉[M].北京:地质出版社,2013:1-129. Li Z H,Kang F X,Liu G A,et al.Ji’nan Geothermal Hot Sp-ring[M].Beijing:Geological Publishing House,2013:1-129. [4] 张卓,成世才,金兴,等.环境同位素技术在确定济南平阴某氡地热井补给来源中的应用[J].山东国土资源,2018,34(7):78-81. Zhang Z,Cheng S C,Jin X,et al.Application of environmental isotope technique in determining recharge source of a radon geothermal well in Pingyin County of Jinan City[J].Shandong Land Res,2018,34(7):78-81. [5] 段乃金,陈刚,宋会军.济南平阴氡温泉水化学成分与同位素特征研究[J].地下水,2019,41(3):14-16. Duan N J,Chen G,Song H J.Study on chemical constituents and isotopic characteristics of hot spring water in Pingyin,Jinan[J].Ground Water,2019,41(3):14-16. [6] 卢兆群,宋会军,程洪柱.应用地热温标估算济南市平阴县大孙庄氡温泉热储温度[J].化工矿产地质,2020,42(1):42-46. Lu Z Q,Song H J,Cheng H Z.Application of geothermometer estimate geothermal reservoir temperature of radon geothermal spring in Dasunzhuang,Pingyin county,Jinan City[J].Geol Chem Mi-ner,2020,42(1):42-46. [7] 于晓静,金兴,尹斐.济南市平阴氡地热水中氟的来源及赋存机理浅析[J].山东国土资源,2017,33(8):46-50. Yu X J,Jin X,Yin F.Primary analysis on the resource and occurrence mechanism of fluorine ion in radon geothermal water in Pingyin of Jinan[J].Shandong Land Res,2017,33(8):46-50. [8] 段乃金,卢兆群,陈刚.济南平阴氡温泉成因机理分析[J].河北地质大学学报,2018,41(6):43-46. Duan N J,Lu Z Q,Chen G.Approach of origin of a radon geothermal spring in Pingyin,Jinan[J].J Hebei GEO Univ,2018,41(6):43-46. [9] 徐军祥,刘桂仪,任书才.山东省地热资源及其开发利用的生态环境意义[C]//中国能源研究会地热专业委员会.全国地热产业可持续发展学术研讨会论文集.北京:中国能源研究会地热专业委员会,2005:81-87. Xu J X,Liu G Y,Ren S C.The eco-environmental significance of geothermal resources and their development and utilization in Shandong Province[C]//Geothermal Professional Committee of China Energy Research Association.Proceedings of National Symposium on Sustainable Development of Geothermal Industry.Beijing:Geothermal Professional Committee of China Energy Research Association,2005:81-87. [10] 尚英男. 环境同位素示踪技术在地热地球化学研究中的应用[J].世界核地质科学,2006,23(1):21-26. Shang Y N.Application of environmental isotope tracing tech-nology to geothermal geochemistry[J].World Nucl Geosci,2006,23(1):21-26. [11] 张卫民. 水文地球化学方法在赣南横径地区地热水成因分析中的应用[J].水文地质工程地质,2001,28(4):45-48. Zhang W M.Application of hydrogeochemical method to the origin analysis of geothermal water in Henjing,South Jiangxi Pro-vince[J].Hydrogeol Eng Geol,2001,28(4):45-48. [12] 柳鉴容,宋献方,袁国富,等.中国东部季风区大气降水δ18O的特征及水汽来源[J].科学通报,2009,54(22):3521-3531. Liu J R,Song X F,Yuan G F,et al.Characteristics of δ18O in precipitation over eastern monsoon China and the water vapor sour-ces[J].Chin Sci Bull,2010,55(2):200-211. [13] 闫晓雪,甘浩男,岳高凡.广东惠州—从化典型地热田水文地球化学特征及成因分析[J].地质论评,2019,65(3):743-754. Yan X X,Gan H N,Yue G F.Hydrogeochemical characteristics and genesis of typical geothermal fileds from Huizhou to Conghua in Guangdong[J].Geol Rev,2019,65(3):743-754. [14] 郝彦珍,潘明,吕勇,等.云南昌宁柯街断裂带温泉水化学特征[J].地质科技情报,2014,33(4):191-196. Hao Y Z,Pan M,Lyu Y,et al.Hydrochemical features of the hot spring in Kejie fault,Changning,Yunnan[J].Geol Sci Technol Inform,2014,33(4):191-196. [15] 袁建飞,邓国仕,徐芬,等.川西南喜德热田地下水水文地球化学特征[J].现代地质,2017,31(1):200-208. Yuan J F,Deng G S,Xu F,et al.Hydrogeochemical characteristics of groundwater in the Xide geothermal field,Southwest Sichuan,China[J].Geoscience,2017,31(1):200-208. [16] Clark I D,Fritz P.Environmental Isotopes in Hydrogeology[M].Boca Raton:Lewis Publishers,1997:352. [17] 卞跃跃,赵丹.四川康定地热田地下热水成因研究[J].地球学报,2018,39(4):491-497. Bian Y Y,Zhao D.Genesis of geothermal waters in the Kangding geothermal field,Sichuan Province[J].Acta Geosci Sin,2018,39(4):491-497. [18] Gibbs R J.Mechanisms controlling world water chemistry[J].Science,1970,170(3962):1088-1090. [19] 刘伟坡,沙娜,程旭学,等.海原县山前地下水化学特征分析[J].人民黄河,2019,41(8):82-87. Liu W P,Sha N,Cheng X X,et al.Study on hydro-geochemical characteristics in piedmont of Haiyuan county[J].Yellow River,2019,41(8):82-87. [20] 陈凯,孙林华.任楼煤矿地下水化学组成及其控制因素分析[J].煤炭科学技术,2019,47(10):240-244. Chen K,Sun L H.Analysis of chemical composition and control factors of groundwater in Renlou coal mine[J].Coal Sci Technol,2019,47(10):240-244. [21] 郎旭娟,蔺文静,刘志明,等.贵德盆地地下热水水文地球化学特征[J].地球科学,2016,41(10):1723-1734. Lang X J,Lin W J,Liu Z M,et al.Hydrochemical characteristics of geothermal water in Guide basin[J].Earth Science,2016,41(10):1723-1734. [22] 单玄龙,蔡壮,郝国丽,等.地球化学温标估算长白山地热系统热储温度[J].吉林大学学报:地球科学版,2019,49(3):662-672. Shan X L,Cai Z,Hao G L,et al.Estimation of thermal storage temperature of geothermal system in Changbai mountain by geothermometers[J].J Jilin Univ:Earth Sci Ed,2019,49(3):662-672. [23] 王莹,周训,于湲,等.应用地热温标估算地下热储温度[J].现代地质,2007,21(4):605-612. Wang Y,Zhou X,Yu Y,et al.Application of geothermometers to calculation of temperature of geothermal reservoirs[J].Geo-science,2007,21(4):605-612. [24] 郑西来,刘鸿俊.地热温标中的水-岩平衡状态研究[J].西安地质学院学报,1996,18(1):74-79. Zheng X L,Liu H J.Study of the water-rock equilibrium state in the application of geothermometer[J].J Xi’an College Geol,1996,18(1):74-79. [25] Giggenbach W F.Geothermal solute equilibria.Derivation of Na-K-Mg-Ca geoindicators[J].Geochim Cosmochim Acta,1988,52(12):2749-2765. [26] 温煜华,王乃昂,朱锡芬,等.天水及其南北地区地热水水化学特征及起源[J].地理科学,2011,31(6):668-673. Wen Y H,Wang N A,Zhu X F,et al.Hydrochemistry of geothermal water in Tianshui and its northern-southern area[J].Sci Geogr Sin,2011,31(6):668-673. [27] Fournier R O.Chemical geothermometers and mixing models for geothermal systems[J].Geothermics,1977,5(1-4):41-50. [28] 杨雷. 重庆市温塘峡背斜地下热水水文地球化学特征研究[D].重庆:西南大学,2012:1-54. Yang L.Study on Hydrogeochemical Features of the Thermal Water at Wentang Gorge Anticline in Chongqing,China[D].Chongqing:Southwest University,2012:1-54. [29] 王云,赵慈平,李其林,等.滇东南楔形构造区典型地热流体地球化学特征研究[J].地震研究,2018,41(4):534-543. Wang Y,Zhao C P,Li Q L,et al.Study on geochemical characte-ristics of geothermal fluid in the wedge-shaped tectonics,Southeast Yunnan[J].Journal of Seismological Research,2018,41(4):534-543.