Abstract:Affected by the collision between Cathaysian Plate and Yangtze Plate, the ancient uplifts around Upper Yangtze Sea area developed during the Silurian period, and the sediment sources in the study area were complex. In order to investigate the sedimentary environment of Silurian strata in Yongshun area of Northwestern Hunan, the authors in this paper studied the REE geochemical characteristics of Silurian sandstone in this area. The results show that the differentiation between LREE and HREE is obvious in samples, with rich LREE and flat HREE. Eu is of obviously negative anomaly, and Ce is normal. The palaeoenvironment of the Silurian period in the study area was anoxic and weak reduction environment, implied by Ceanom results. The geochemical characteristics of REE indicate that the sedimentary rate of the Silurian period in the study area is fast. Combined with structural features and achievements in palaeogeography of predecessors, the authors in this paper suggest that the provenance of the study area comes from the sedimentary rock in Xuefeng Mountain uplift, which can provide some reference for lithofacies paleogeography restoration of Silurian in Northwestern Hunan.
[1] 王根贤,陈必河,郑正福,等.湖南及邻区志留纪兰多弗里世鲁丹期至埃隆期岩相古地理及加里东期板块构造演化[J].地质论评,2021,67(6):1557-1585. Wang G X,Chen B H,Zheng Z F,et al.Rhuddanian-Aeronian (Llandovery,Silurian) lithofacies palaeogeography of Hunan Province and its adjacent region and Caledonian plate tectonic evolution[J].Geol Rev,2021,67(6):1557-1585. [2] 徐胜林,袁文俊,侯明才,等.上扬子地台南缘早志留世埃隆期碳酸盐岩岩石学特征及沉积环境[J].岩石学报,2017,33(4):1357-1368. Xu S L,Yuan W J,Hou M C,et al.Petrological characteristics and sedimentary environment of carbonate during Aeronlian stage of Early Silurian in the southern margin of Yangtze Craton[J].Acta Petrol Sin,2017,33(4):1357-1368. [3] 李斌,胡博文,石小虎,等.湘西地区志留纪沉积体系及典型前陆盆地的形成模式研究[J].地学前缘,2015,22(6):167-176. Li B,Hu B W,Shi X H,et al.Study on the Silurian sedimentary system of Western Hunan and the formation mode of typical foreland basin[J].Earth Sci Front,2015,22(6):167-176. [4] 文玲,胡书毅,田海芹.扬子地区志留纪岩相古地理与石油地质条件研究[J].石油勘探与开发,2002,29(6):11-14. Wen L,Hu S Y,Tian H Q.Lithofacies paleogeography and petroleum geology of the Silurian in Yangtze area[J].Petrol Explor Dev,2002,29(6):11-14. [5] 万方,许效松.川滇黔桂地区志留纪构造-岩相古地理[J].古地理学报,2003,5(2):180-186. Wan F,Xu X S.Tectonic-lithofacies palaeogeography of the Silurian in Sichuan-Yunnan-Guizhou-Guangxi region[J].J Palaeogeogr,2003,5(2):180-186. [6] 孙莎莎,芮昀,董大忠,等.中、上扬子地区晚奥陶世一早志留世古地理演化及页岩沉积模式[J].石油与天然气地质,2018,39(6):1087-1106. Sun S S,Rui Y,Dong D Z,et al.Paleogeographic evolution of the Late Ordovician-Early Silurian in Upper and Middle Yangtze regions and depositional model of shale[J].Oil Gas Geol,2018,39(6):1087-1106. [7] 戎嘉余,王怿,詹仁斌,等.中国志留纪综合地层和时间框架[J].中国科学:地球科学,2019,49(1):93-114. Rong J Y,Wang Y,Zhan R B,et al.Silurian integrative stratigraphy and timescale of China[J].Sci China Earth Sci,2019,62(1):89-111. [8] 陈知,陈波.三峡地区埃迪卡拉纪的浅海氧化还原环境变化:来自碳酸盐岩Ce异常的证据[J].地层学杂志,2022,46(2):109-117. Chen Z,Chen B.Ediacaran shallow-marine redox conditions in the Yangtze Gorges area:Evidence from carbonate cerium anomalies[J].J Stratigr,2022,46(2):109-117. [9] 肖盼,郭建华,李杰,等.湖南早志留世沉积演化及页岩气勘探前景[J].沉积与特提斯地质,2017,37(1):79-87. Xiao P,Guo J H,Li J,et al.Sedimentary evolution and shale gas exploration potential of the Lower Silurian strata in Hunan[J].Sediment Geol Tethyan Geol,2017,37(1):79-87. [10] 王传尚,汪啸风,危凯,等.湘鄂西地区志留纪海平面变化与层序地层划分对比[J].华南地质,2022,38(1):67-78. Wang C S,Wang X F,Wei K,et al.The Silurian sea level changes and sequence stratigraphic division and correlation in Western Hunan and Hubei Province[J].South China Geol,2022,38(1):67-78. [11] 王怿,戎嘉余,唐鹏,等.华南古生代中期地层界面的特征与大地构造意义[J].中国科学:地球科学,2021,51(2):218-240. Wang Y,Rong J Y,Tang P,et al.Characteristics of major hiatus in middle Paleozoic rocks of South China and their significance of geotectonics[J].Sci Sin Terrae,2021,51(2):218-240. [12] 李双建,肖开华,沃玉进,等.湘西、黔北地区志留系稀土元素地球化学特征及其地质意义[J].现代地质,2008,22(2):273-280. Li S J,Xiao K H,Wo Y J,et al.REE geochemical characteristics and their geological signification in Silurian,West of Hunan Province and North of Guizhou Province[J].Geoscience,2008,22(2):273-280. [13] 王国茹,陈洪德,朱志军,等.川东南—湘西地区志留系小河坝组砂岩稀土元素特征及其地质意义[J].石油实验地质,2010,32(5):487-495. Wang G R,Chen H D,Zhu Z J,et al.The characteristics and geological implications of rare earth elements in sandstone of lower Silurian Xiaoheba Formation in the Southeastern Sichuan -Western Hunan[J].Petrol Geol Exp,2010,32(5):487-495. [14] 梁恩云,刘耀荣,邹光均,等.张家界地区志留系岩石地球化学与构造背景[J].中国地质调查,2017,4(6):58-65. Liang E Y,Liu Y R,Zou G J,et al.Geochemical characteristics and tectonic setting of Silurian rocks in Zhangjiajie area[J].Geol Survey China,2017,4(6):58-65. [15] 周恳恳,牟传龙,梁薇,等.湘西北龙山、永顺地区龙马溪组潮控三角洲沉积的发现——志留纪“雪峰隆起”形成的新证据[J].沉积学报,2014,32(3):468-477. Zhou K K,Mou C L,Liang W,et al.Tide-dominated deltaic deposits in Lungamachi Formation,Longshan-Yongshun regions,Northwestern Hunan:The initial sedimentary responses to outset of “Xuefeng uplift”[J].Acta Sedimentol Sin,2014,32(3):468-477. [16] 王辰,刘建朝,张海东,等.湘西花垣地区奥陶—志留系沉积岩稀土元素地球化学特征及地质意义[J].矿物岩石地球化学通报,2017,36(3):516-522. Wang C,Liu J C,Zhang H D,et al.REE geochemical characteristics of Ordovician-Silurian sedimentary rocks in the Huayuan area,Hunan Province and their geological significances[J].Bull Mineral Petrol Geochem,2017,36(3):516-522. [17] 苏文博,李志明,Ettensohn F R,等.华南五峰组—龙马溪组黑色岩系时空展布的主控因素及其启示[J].地球科学-中国地质大学学报,2007,32(6):819-827. Su W B,Li Z M,Ettensohn F R,et al.Distribution of black shale in the Wufeng-Longmaxi Formations (Ordovician-Silurian),South China:Major controlling factors and implications[J].Earth Sci-J China Univ Geosci,2007,32(6):819-827. [18] 陈洪德,庞林,倪新锋,等.中上扬子地区海相油气勘探前景[J].石油实验地质,2007,29(1):13-18. Chen H D,Pang L,Ni X F,et al.New brief remarks on hydrocarbon prospecting of marine strata in the middle and upper Yangtze region[J].Petrol Geol Exp,2007,29(1):13-18. [19] 王中刚,于学远,赵振华.稀土元素地球化学[M].北京:科学出版社,1989:143-223. Wang Z G,Yu X Y,Zhao Z H.Rare Earth Element Geochemi-stry[M].Beijing:Science Press,1989:143-223. [20] 韩吟文,马振东.地球化学[M].北京:地质出版社,2003:189-210. Han Y W,Ma Z D.Geochemistry[M].Beijing:Geological Publishing Press,2003:189-210. [21] 毛光周,刘池洋.地球化学在物源及沉积背景分析中的应用[J].地球科学与环境学报,2011,33(4):337-348. Mao G Z,Liu C Y.Application of geochemistry in provenance and depositional setting analysis[J].J Earth Sci Environ,2011,33(4):337-348. [22] 刘岫峰. 沉积岩实验室研究方法[M].北京:地质出版社,1991:213-218. Liu X F.Laboratory Research Methods of Sedimentary Rocks[M].Beijing:Geology Press,1991:213-218. [23] Shields G,Stille P.Diagenetic constraints on the use of cerium anomalies as palaeoseawater redox proxies:An isotopic and REE study of Cambrian phosphorites[J].Chem Geol,2001,175(1/2):29-48. [24] Morad S,Felitsyn S.Identification of primary Ce-anomaly signatures in fossil biogenic apatite:implication for the Cambrian oceanic anoxia and phosphogenesis[J].Sediment Geol,2001,143(3/4):259-264. [25] Elderfield H,Greaves M J.The rare earth elements in seawater[J].Nature,1982,296(5854):214-219. [26] 赵振华. 微量元素地球化学原理[M].北京:科学出版社,1997:143-223. Zhao Z H.Principles of Trace Element Geochemistry[M].Beijing:Science Press,1997:143-223. [27] 杨守业,李从先.REE示踪沉积物物源研究进展[J].地球科学进展,1999,14(2):164-167. Yang S Y,Li C X.Research progress in REE tracer for sediment source[J].Adv Earth Sci,1999,14(2):164-167. [28] McLennan S M.Rare earth elements in sedimentary rocks; influence of provenance and sedimentary processes[J].Rev Mineral Geochem,1989,21(1):169-200. [29] Bhatia M R,Crook K A W.Trace element characteristics of graywackes and tectonic setting discrimination of sedimentary basins[J].Contribut Mineral Petrol,1986,92(2):181-193. [30] McLennan S M,Hemming S R,Taylor S R,et al.Early Proterozoic crustal evolution:geochemical and NdPb isotopic evidence from metasedimentary rocks,southwestern North America[J].Geochim Cosmochim Acta,1995,59(6):1153-1177. [31] Bhatia M R.Plate tectonics and geochemical composition of sandstones[J].J Geol,1983,91(6):611-627. [32] 侯伟,刘招君,何玉平,等.砂岩稀土元素地球化学特征在沉积物源区分析中的应用——以中国东北漠河盆地中侏罗统为例[J].沉积学报,2010,28(2):285-293. Hou W,Liu Z J,He Y P,et al.Application of REE geochemical characteristics of sandstone to study on provenance:A case from the middle Jurassic of Mohe basin in Northeast China[J].Acta Sedimentol Sin,2010,28(2):285-293. [33] 朱志军,陈洪德.川东南地区志留系小河坝组砂岩特征及物源分析[J].吉林大学学报:地球科学版,2012,42(6):1590-1600. Zhu Z J,Chen H D.Sandstone characteristics and provenance analysis of the sandstone in Silurian Xiaoheba Formation in Southeastern Sichuan province,China[J].J Jilin Univ:Earth Sci Ed,2012,42(6):1590-1600. [34] 侯明才,陈洪德,陈安清.江南—雪峰隆起对川东南—黔南凹陷石牛栏期沉积古地理的制约[J].成都理工大学学报:自然科学版,2010,37(4):395-400. Hou M C,Chen H D,Chen A Q.Constraints of the Jiangnan-Xuefeng upheaval to the depositional system and paleogeography distribution of Southeast Sichuan-South Guizhou depression during Shiniulan Period[J].J Chengdu Univ Technol:Sci Technol Ed,2010,37(4):395-400.