Research progress and prospect of environmental geochemical investigation of persistent organic pollutants
MA Jiabao1, LIU Siwen1, WEI Jixin1,2, HUANG Yi1, MA Chenge1,3
1. National Research Center for Geoanalysis, Beijing 100037, China; 2. China University of Geosciences (Beijing), Beijing 100083,China; 3. China University of Geosciences (Wuhan), Hubei Wuhan 430074,China
Abstract:The environmental geochemical survey of persistent organic pollutants (POPs) is an important mean to study and master its chemical properties, migration, transformation and environmental fate. Three inclusions were summarized based on the research progress of environmental geochemical investigation and research of POPs in recent years. ① POPs generally have characteristic of environmental refractory, long-distance migration, bioaccumulation and high biological toxicity, and the concentration data of POPs have been widely reported in different environmental media around the world. The POPs have become an important risk that endangers ecosystems and human health, with the historical accumulation and continuous release. According to the existing survey and monitoring data, the concentration levels of POPs from test samples of partial water bodies and soil are currently high in China. ② POPs can migrate among different environmental interfaces such as atmosphere-water-sediment or atmosphere-soil, then it can contaminate ground water and migrate to every corner of the surface system. This migration and transformation are closely related to the composition of POPs and the physical and chemical properties, temperature, pH and other factors of the environmental medium. ③ there is a short of continuous and systematic investigation and monitoring about some types of POPs in environmental media such as the atmosphere, water bodies, sediment, and soil, the relevant institutions in China, which results in difficult systematic analysis and research on the pollution levels and long-term changes of POPs. It is suggested that the long-term dynamic monitoring of the atmosphere soil water interface should be strengthened and the monitoring and analysis methods, standards and methods of POPs should be improved. The systematic environmental geochemical comprehensive analysis and research also should be carried out to provide theoretical and practical support for the implementation of environmental pollution prevention and ecological restoration.
[1] Bakirtas T,Akpolat A G.The relationship between energy consumption,urbanization,and economic growth in new emerging-market countries[J].Energy,2018,147:110-121. [2] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 14848—2017 地下水质量标准[S].北京:中国标准出版社,2017. General Administration of Quality Supervision,Inspection and Quarantine of the People’s Republic of China,Standardization Administration of the People’s Republic of China.GB/T 14848—2017 Standard for Groundwater Quality[S].Beijing:Standards Press of China,2017. [3] 国家环境保护总局,国家质量监督检验检疫总局.GB 3838—2002 地表水环境质量标准[S].北京:中国环境科学出版社,2002. State Environmental Protection Administration,General Administration of Quality Supervision,Inspection and Quarantine of the People’s Republic of China.GB 3838—2002 Environmental Quality Standards for Surface Water[S].Beijing:China Environmental Press,2002. [4] 生态环境部,国家市场监督管理总局.GB 15618—2018 土壤环境质量农用地土壤污染风险管控标准(试行)[S].北京:环境科学出版社,2019. Ministry of Ecology and Environment,General Administration of Quality Supervision,Inspection and Quarantine of the People’s Republic of China.GB 15618—2018 Soil Environmental Quality Risk Control Standard for Soil Contamination of Agricultural Land[S].Beijing:China Environmental Press,2019. [5] 中华人民共和国国土资源部.DZ/T 0288—2015 区域地下水污染调查评价规范[S].北京:中国标准出版社,2015. Ministry of Land and Resources of the People’s Republic of China.DZ/T 0288—2015 Specification for Regional Groundwater Contamination Investigation and Evaluation[S].Beijing:Standards Press of China,2015. [6] Ashraf M A.Persistent organic pollutants (POPs):a global issue,a global challenge[J].Environmental Science and Pollution Research,2017,24(5):4223-4227. [7] Nguyen V H,Smith S M,Wantala K,et al.Photocatalytic remediation of persistent organic pollutants (POPs):a review[J].Arabian Journal of Chemistry,2020,13(11):8309-8337. [8] Berger U,Ost N,Sättler D,et al.Assessment of persistence,mobility and toxicity (PMT) of 167 REACH Registered Substances[M].German Environment Agency(UBA),2018:1-60. [9] Vaalgamaa S,Vähätalo A V,Perkola N,et al.Photochemical reactivity of perfluorooctanoic acid (PFOA) in conditions representing surface water[J].Science of the Total Environment,2011,409(16):3043-3048. [10] Beyer A,Mackay D,Matthies M,et al.Assessing long-range transport potential of persistent organic pollutants[J].Environmental Science & Technology,2000,34(4):699-703. [11] Alharbi O M L,Basheer A A,Khattab R A,et al.Health and environmental effects of persistent organic pollutants.Journal of Molecular Liquids,2018,263:442-453. [12] Baek S Y,Choi S D,Chang Y S.Three-year atmospheric monitoring of organochlorine pesticides and polychlorinated biphenyls in polar regions and the South Pacific[J].Environmental Science & Technology,2011,45(10):4475-4482. [13] Ma Y X,Adelman D A,Bauerfeind E,et al.Concentrations and water mass transport of legacy POPs in the Arctic Ocean[J].Geophysical Research Letters,2018,45(23):12972-12981. [14] 张荣秋,董纯明,盛华芳,等.白令海和楚科奇海表层沉积物中多环芳烃降解微生物多样性[J].海洋学报,2014,36(4):52-61. Zhang R Q,Dong C M,Sheng H F,et al.Biodiversity of polycyclic aromatic hydrocarbon-degrading bacteria from surficial sediments of the Bering Sea and Chukchi Sea in the Arcti[J].Acta Oceanologica Sinica,2014,36(4):52-61. [15] Tomy G T,Budakowski W,Halldorson T,et al.Fluorinated organic compounds in an eastern Arctic marine food web[J].Environmental Science & Technology,2004,38(24):6475-6481. [16] Cabrerizo A,Galbán-Malagón C,Del Vento S,et al.Sources and fate of polycyclic aromatic hydrocarbons in the Antarctic and Southern Ocean atmosphere[J].Global Biogeochemical Cycles,2014,28(12):1424-1436. [17] Cao S K,Na G S,Li R J,et al.Fate and deposition of polycyclic aromatic hydrocarbons in the Bransfield Strait,Antarctica[J].Marine Pollution Bulletin,2018,137:533-541. [18] Curtosi A,Pelletier E,Vodopivez C L,et al.Distribution of PAHs in the water column,sediments and biota of Potter Cove,South Shetland Islands,Antarctica[J].Antarctic Science,2009,21(4):329-339. [19] 叶新荣,陈立红,张荣保,等.气相色谱法分析南极贼鸥粪土层中的多氯联苯和有机氯农药[J].环境化学,2013,32(9):1805-1806. Ye X R,Chen L H,Zhang R B,et al.Analysis of polychlorinated biphenyls and organochlorine pesticides in antarctic skua feces by gas chromatography[J].Environmental Chemistry,2013,32(9):1805-1806. [20] Strobel A,Schmid P,Burkhardt-Holm P,et al.Persistent organic pollutants in red- and white-blooded High-Antarctic notothenioid fish from the remote Weddell Sea[J].Chemosphere,2018,193:213-222. [21] Krahn M M,Pitman R L,Burrows D G,et al.Use of chemical tracers to assess diet and persistent organic pollutants in Antarctic type C killer whales[J].Marine Mammal Science,2008,24(3):643-663. [22] Nicolas P,Begoña J,Jose L R,et al.First evidence of legacy chlorinated POPs bioaccumulation in Antarctic sponges from the Ross sea and the South Shetland Islands[J].Environmental pollution,2023,329:1-9. [23] Galbán-Malagón C J,Del Vento S,Berrojalbiz N,et al.Polychlorinated biphenyls,hexachlorocyclohexanes and hexachlorobenzene in seawater and phytoplankton from the southern ocean (Weddell,South Scotia,and Bellingshausen Seas)[J].Environmental Science & Technology,2013,47(11):5578-5587. [24] 张干,李军,田崇国,等.持久性有机污染物的地球化学[M].北京:科学出版社,2019:11-14. Zhang G,Li J,Tian C G,et al.Environmental Geochemistry of Persistent Organic Pollutants[M].Beijing:Science Press,2019:11-14. [25] Poma G,Cuykx M,Amato E,et al.Evaluation of hazardous chemicals in edible insects and insect-based food intended for human consumption[J].Food and Chemical Toxicology,2017,100:70-79. [26] 刘东红,陶玉强,周文佐.持久性有机污染物在中国湖泊生物中分布与富集的研究进展[J].湖泊科学,2018,30(3):581-596. Liu D H,Tao Y Q,Zhou W Z.Distribution and accumulation of persistent organic pollutants in aquatic organisms of Chinese lakes[J].Journal of Lake Sciences,2018,30(3):581-596. [27] 范夏瑞,王紫薇,李垚,等.我国持久性有机污染物质的暴露及健康风险[C]//中国毒理学会环境与生态毒理学专业委员会第七届学术研讨会议论文摘要集.贵阳:中国毒理学会,2021:34. Fan X R,Wang Z W,Li Y,et al.Exposure and Health Risks of Persistent Organic Pollutants in China[C]//Proceedings of the 7th Academic Seminar of the Professional Committee of Environmental and Ecotoxicology.Guiyang:Chinese Society of Toxicology,2021:34. [28] Krätschmer K,Malisch R,Vetter W.Chlorinated paraffin levels in relation to other persistent organic pollutants found in pooled human milk samples from primiparous mothers in 53 countries[J].Environmental Health Perspectives,2021,129(8):087004. [29] Tsygankov V Y,Gumovskaya Y P,Gumovskiy A N,et al.Bioaccumulation of POPs in human breast milk from south of the Russian Far East and exposure risk to breastfed infants[J].Environmental Science and Pollution Research,2020,27(6):5951-5957. [30] 王芹,张秋丰,胡跃城,等.渤海湾持久性有机污染物的分布特征及来源解析[J].海洋环境科学,2013,32(2):271-275. Wang Q,Zhang Q F,Hu Y C,et al.Distribution and sources of persistent organic pollutants in Bohai Bay[J].Marine Environmental Science,2013,32(2):271-275. [31] 胡晴晖. 湄洲湾水体中持久性有机污染物的污染特征与风险评估[J].中国环境科学,2014,34(10):2536-2544. Hu Q H.Occurrence and ecological risk assessment of persistent organic pollutants in Meizhou Bay[J].China Environmental Science,2014,34(10):2536-2544. [32] 龚雄虎,丁琪琪,金苗,等.升金湖水体优先污染物筛选与风险评价[J].环境科学,2021,42(10):4727-4738. Gong X H,Ding Q Q,Jin M,et al.Screening of priority pollutants and risk assessment for surface water from Shengjin Lake[J].Environmental Science,2021,42(10):4727-4738. [33] 高秋生,焦立新,杨柳,等.白洋淀典型持久性有机污染物污染特征与风险评估[J].环境科学,2018,39(4):1616-1627. Gao Q S,Jiao L X,Yang L,et al.Occurrence and ecological risk assessment of typical persistent organic pollutants in Baiyangdian Lake[J].Environmental Science,2018,39(4):1616-1627. [34] 刘少颖,黄希汇,胡柯君,等.钱塘江水体和鱼体内农药类持久性有机污染物残留水平及积累特征分析[J].中国卫生检验杂志,2020,30(11):1284-1288. Liu S Y,Huang X H,Hu K J,et al.Analysis of the residual levels and accumulation characteristics of pesticide persistent organic pollutants in water and fish in the Qiantang River[J].Chinese Journal of Health Laboratory Technology,2020,30(11):1284-1288. [35] 谷先坤. 多环芳烃和有机氯农药在巢湖的赋存及其生物积累放大效应研究[D].南京:中国科学院南京地理与湖泊研究所,2017. Gu X K.Study on the Occurrence and Bioaccumulation Amplification Effect of Polycyclic Aromatic Hydrocarbons and Organochlorine Pesticides in Chaohu Lake[D].Nanjing:Nanjing Institute of Geography and Limnology,Chinese Academy of Sciences,2017. [36] 单德鑫,刘璐瑶,樊洪瑞,等.辽河流域水体中持久性有机物污染特征分析[J].合肥学院学报:综合版,2018,35(2):31-37. Shan D X,Liu L Y,Fan H R,et al.Analysis on characteristics of persistent organic pollutants in Liaohe River Basin[J].Journal of Hefei University (Comprehensive Edition),2018,35(2):31-37. [37] 张坤锋,付青,涂响,等.武汉典型饮用水水源中典型POPs污染特征与健康风险评估[J].环境科学,2021,42(12):5836-5847. Zhang K F,Fu Q,Tu X,et al.Pollution characteristics and risk assessment of typical POPs in typical drinking water sources in Wuhan[J].Environmental Science,2021,42(12):5836-5847. [38] 周涛,韩彬,徐亚岩,等.南中国海海水中有机氯农药和多氯联苯的含量及分布特征[J].岩矿测试,2014,33(1):90-95. Zhou T,Han B,Xu Y Y,et al.Concentrations and distribution characteristics of organochlorine pesticides and polychlorinated biphenyls in seawaters of the South Sea[J].Rock and Mineral Analysis,2014,33(1):90-95. [39] Wang C L,Zou X Q,Zhao Y F,et al.Distribution,sources,and ecological risk assessment of polycyclic aromatic hydrocarbons in the water and suspended sediments from the middle and lower reaches of the Yangtze River,China[J].Environmental Science and Pollution Research,2016,23(17):17158-17170. [40] 任亚军. 扬州城区水体和表层底泥中3类持久性有机污染物时空分布及风险评价[D].扬州:扬州大学,2018. Ren Y J.Temporal and Spatial Distribution and Risk Assessment of Three Pollutants in Water and Surface Sediments of Yangzhou Urban Area[D].Yangzhou:Yangzhou University,2018. [41] 王乙震,周绪申,林超,等.南运河生态修复水体有机污染物的污染特征[J].环境化学,2016,35(2):383-392. Wang Y Z,Zhou X S,Lin C,et al.Pollution characteristics of organic pollutants in the ecologically restored water of South Canal[J].Environmental Chemistry,2016,35(2):383-392. [42] 员晓燕,杨玉义,李庆孝,等.中国淡水环境中典型持久性有机污染物(POPs)的污染现状与分布特征[J].环境化学,2013,32(11):2072-2081. Yuan X Y,Yang Y Y,Li Q X,et al.Present situation and distribution characteristics of persistent organic pollutants in freshwater in China[J].Environmental Chemistry,2013,32(11):2072-2081. [43] 陶玉强,赵睿涵.持久性有机污染物在中国湖库水体中的污染现状及分布特征[J].湖泊科学,2020,32(2):309-324. Tao Y Q,Zhao R H.Occurrence and distribution of persistent organic pollutants in water of Chinese lakes and reservoirs[J].Journal of Lake Sciences,2020,32(2):309-324. [44] Dai G H,Liu X H,Liang G,et al.Distribution of organochlorine pesticides (OCPs) and poly chlorinated biphenyls (PCBs) in surface water and sediments from Baiyangdian Lake in North China[J].Journal of Environmental Sciences,2011,23(10):1640-1649. [45] Unyimadu J P,Osibanjo O,Babayemi J O.Selected persistent organic pollutants (POPs) in water of River Niger:occurrence and distribution[J].Environmental Monitoring and Assessment,2018,190(1):6. [46] 穆希岩,黄瑛,李学锋,等.我国水体中持久性有机污染物的分布及其对鱼类的风险综述[J].农药学学报,2016,18(1):12-27. Mu X Y,Huang Y,Li X F,et al.The occurrence of persistent organic pollutants in China and their environmental risk to fish:a review[J].Chinese Journal of Pesticide Science,2016,18(1):12-27. [47] 吕雪艳,孙媛媛,于志国,等.全氟辛酸在沉积物-水界面污染及吸附迁移行为研究进展[J].应用生态学报,2021,32(11):4147-4155. Lyu X Y,Sun Y Y,Yu Z G,et al.Research progress on the pollution,adsorption,and transport of perfluorooctanoic acid (PFOA) at the sediment-water interface[J].Chinese Journal of Applied Ecology,2021,32(11):4147-4155. [48] Sun R,Wu M H,Tang L,et al.Perfluorinated compounds in surface waters of Shanghai,China:source analysis and risk assessment[J].Ecotoxicology and Environmental Safety,2018,149:88-95. [49] Chen X W,Zhu L Y,Pan X Y,et al.Isomeric specific partitioning behaviors of perfluoroalkyl substances in water dissolved phase,suspended particulate matters and sediments in Liao River Basin and Taihu Lake,China[J].Water Research,2015,80:235-244. [50] Huang M,Li Z W,Huang B,et al.Investigating binding characteristics of cadmium and copper to DOM derived from compost and rice straw using EEM-PARAFAC combined with two-dimensional FTIR correlation analyses[J].Journal of Hazardous Materials,2018,344:539-548. [51] 任东,杨小霞,马晓冬,等.DOM结构特征及其对17β-雌二醇光降解的影响[J].中国环境科学,2015,35(5):1375-1383. Ren D,Yang X X,Ma X D,et al.Structural characteristics of DOM and its effects on the photodegradation of 17β-estradiol[J].China Environmental Science,2015,35(5):1375-1383. [52] 谢冰心,王姝,孙辉,等.溶解性有机质对持久性有机污染物环境行为的影响研究进展[J].环境污染与防治,2020,42(12):1563-1568. Xie B X,Wang S,Sun H,et al.Impacts of dissolved organic matter on the environmental behavior of persistent organic pollutants:a review[J].Environmental Pollution & Control,2020,42(12):1563-1568. [53] 许妍,陈佳枫,徐磊,等.白洋淀表层沉积物中有机氯农药和全多氯联苯的分布特征及风险评估[J].湖泊科学,2020,32(3):654-664. Xu Y,Chen J F,Xu L,et al.Distribution and risk assessment of organochlorine pesticides and polychlorinated biphenyls in surficial sediments from Lake Baiyangdian[J].Journal of Lake Sciences,2020,32(3):654-664. [54] 李慧,李捷,宋鹏,等.东北小兴凯湖沉积物POPs污染特征及生态风险评价[J].环境科学,2021,42(1):147-158. Li H,Li J,Song P,et al.Characteristics and ecological risk assessment of POPs pollution in sediments of Xiaoxingkai Lake in the Northeast China[J].Environmental Science,2021,42(1):147-158. [55] 朱冰清,高占啟,王骏飞,等.太湖主要入湖河流多溴联苯醚和有机磷阻燃剂污染与风险评价[J].环境监控与预警,2020,12(5):124-131. Zhu B Q,Gao Z Q,Wang J F,et al.Contamination level and ecological Risk assessment of polybrominated diphenyl ethers (PBDEs) and organophosphorus flame retardants (OPFRs) in main inflow Rivers of Taihu Lake[J].Environmental Monitoring and Forewarning,2020,12(5):124-131. [56] 姜丽丽,朱洁羽,王远坤,等.太湖饮用水源地多环芳烃分布特征和溯源分析[J].南京大学学报:自然科学,2016,52(2):361-369. Jiang L L,Zhu J Y,Wang Y K,et al.Distribution characteristics and source identification analysis of polycyclic aromatic hydrocarbons in drinking water sources in Taihu Lake Basin[J].Journal of Nanjing University (Natural Sciences),2016,52(2):361-369. [57] 张文博,刘宾绪,江涛,等.环渤海渔港沉积物多环芳烃的污染特征和生态风险评价[J].环境化学,2022,41(2):561-571. Zhang W B,Liu B X,Jiang T,et al.Pollution characteristics and ecological risk assessment of polycyclic aromatic hydrocarbons in sediments from fishing ports along the coast of Bohai Sea[J].Environmental Chemistry,2022,41(2):561-571. [58] 李胜生,谭浩,陈园园,等.升金湖湿地保护区表层沉积物中持久性有机污染物残留特征[J].安徽农业科学,2018,46(12):69-73,117. Li S S,Tan H,Chen Y Y,et al.Characteristics of residual persistent organic pollutants in surface sediments of Shengjinhu Wetland reserve[J].Journal of Anhui Agricultural Sciences,2018,46(12):69-73,117. [59] 鲁垠涛,刘明丽,刘殷佐,等.长江表层土壤多氯联苯污染特征及风险评价[J].中国环境科学,2018,38(12):4617-4624. Lu Y T,Liu M L,Liu Y Z,et al.Characteristics and health risk assessment of polychlorinated biphenyls in surface soil of the Yangtze River[J].China Environmental Science,2018,38(12):4617-4624. [60] 刘嘉烈,石运刚,唐娜,等.重庆长江流域鲫鱼和沉积物中17种全氟化合物污染特征[J].环境化学,2020,39(12):3450-3461. Liu J L,Shi Y G,Tang N,et al.Pollution characteristics of seventeen per- and polyfluoroalkyl substances in fish and sediments of Yangtze River Basin in Chongqing City[J].Environmental Chemistry,2020,39(12):3450-3461. [61] 倪余文,陈吉平,张雪萍,等.辽河干流沉积物中多氯联苯的水平与污染特点[C]//第三届全国环境化学学术大会论文集.厦门:中国化学会,2011:68. Ni Y W,Chen J P,Zhang X P,et al.Levels and Pollution Characteristics of Polychlorinated Biphenyls in Sediments of the Liaohe River Mainstream[C]//Proceedings of the Third National Conference on Environmental Chemistry.Xiamen:Chinese Chemical Society,2011:68. [62] 张嘉雯,魏健,吕一凡,等.衡水湖沉积物中典型持久性有机污染物污染特征与风险评估[J].环境科学,2020,41(3):1357-1367. Zhang J W,Wei J,LüY F,et al.Occurrence and ecological Risk assessment of typical persistent organic pollutants in Hengshui Lake[J].Environmental Science,2020,41(3):1357-1367. [63] Wu L P,Moses S,Liu Y Q,et al.A concept for studying the transformation reaction of hexachlorocyclohexanes in food webs using multi-element compound-specific isotope analysis[J].Analytica Chimica Acta,2019,1064:56-64. [64] 陈社军,麦碧娴,曾永平,等.珠江三角洲及南海北部海域表层沉积物中多溴联苯醚的分布特征[J].环境科学学报,2005,25(9):1265-1271. Chen S J,Mai B X,Zeng Y P,et al.Polybrominated diphenyl ethers (PBDEs) in surficial sediments of the Pearl River Delta and adjacent South China Sea[J].Acta Scientiae Circumstantiae,2005,25(9):1265-1271. [65] Zheng B H,Zhao X R,Liu L S,et al.Effects of hydrodynamics on the distribution of trace persistent organic pollutants and macrobenthic communities in Bohai Bay[J].Chemosphere,2011,84(3):336-341. [66] 冯秋园,吴桐,万祎,等.持久性有机污染物(POPs)在水生生态系统中的环境行为[J].北京大学学报:自然科学版,2017,53(3):588-596. Feng Q Y,Wu T,Wan Y,et al.Environmental behavior of persistent organic pollutants (POPs) in aquatic ecosystem[J].Acta Scientiarum Naturalium Universitatis Pekinensis,2017,53(3):588-596. [67] Nagy A S,Szabó J,Vass I.Occurrence and distribution of polycyclic aromatic hydrocarbons in surface water and sediments of the Danube River and its tributaries,Hungary[J].Journal of Environmental Science and Health,Part A,2014,49(10):1134-1141. [68] Dachs J,Lohmann R,Ockenden W A,et al.Oceanic biogeochemical controls on global dynamics of persistent organic pollutants[J].Environmental Science & Technology,2002,36(20):4229-4237. [69] Dachs J,Eisenreich S J,Hoff R M.Influence of eutrophication on air-water exchange,vertical fluxes,and phytoplankton concentrations of persistent organic pollutants[J].Environmental Science & Technology,2000,34(6):1095-1102. [70] Sandy A L,Guo J,Miskewitz R J,et al.Fluxes of polychlorinated biphenyls volatilizing from the Hudson River,New York measured using micrometeorological approaches[J].Environmental Science &Technology,2012,46(2):885-891. [71] Wong F,Hung H,Dryfhout-Clark H,et al.Time trends of persistent organic pollutants (POPs) and Chemicals of Emerging Arctic Concern (CEAC) in Arctic air from 25 years of monitoring[J].Science of the Total Environment,2021,775:145109. [72] Larsson P,Andersson A,Broman D,et al.Persistent organic pollutants (POPs) in pelagic systems[J].Ambio:A Journal of the Human Environment,2000,29(5):202-209. [73] Menone M L,Miglioranza K S B,Iribarne O,et al.The role of burrowing beds and burrows of the SW Atlantic intertidal crab Chasmagnathus granulata in trapping organochlorine pesticides[J].Marine Pollution Bulletin,2004,48(3-4):240-247. [74] 亓学奎,马召辉,王英,等.有机氯农药在太湖水体-沉积物中的交换特征[J].生态环境学报,2014,23(12):1958-1963. Qi X K,Ma Z H,Wang Y,et al.Water-to-sediment exchange of organochlorine pesticides in Taihu Lake[J].Ecology and Environmental Sciences,2014,23(12):1958-1963. [75] Schulze S,Zahn D,Montes R,et al.Occurrence of emerging persistent and mobile organic contaminants in European water samples[J].Water Research,2019,153:80-90. [76] Sepulvado J G,Blaine A C,Hundal L S,et al.Occurrence and fate of perfluorochemicals in soil following the land application of municipal biosolids[J].Environmental Science & Technology,2011,45(19):8106-8112. [77] Redon P O,Jolivet C,Saby N P A,et al.Occurrence of natural organic chlorine in soils for different land uses[J].Biogeochemistry,2013,114(1-3):413-419. [78] Bentum J K,Essumang D K,Dodoo D K.Lindane and propuxur residues in the top soils of some cocoa growing areas in five districts of the Central region of Ghana[J].Bulletin of the Chemical Society of Ethiopia,2006,20(2):193-199. [79] 江萍,赵平,万洪富,等.珠江三角洲典型地区表层农田土壤中多氯联苯残留状况[J].土壤,2011,43(6):948-953. Jiang P,Zhao P,Wan H F,et al.Concentrations of PCBs in agricultural soils of typical regions in Pearl River Delta[J].Soils,2011,43(6):948-953. [80] 马妍,程芦,阮子渊,等.近20年中国表层土壤中多环芳烃时空分布特征及源解析[J].环境科学,2021,42(3):1065-1072. Ma Y,Cheng L,Ruan Z Y,et al.Polycyclic aromatic hydrocarbons in surface soil of China (2000-2020):temporal and spatial distribution,influencing factors[J].Environmental Science,2021,42(3):1065-1072. [81] 周燕. 西安市居民区土壤多环芳烃来源及健康风险评价[J].环境科学导刊,2019,38(6):71-77. Zhou Y.Pollution,sources and health risk assessment of polycyclic aromatic hydrocarbons in soils in residential areas of Xi’an City[J].Environmental Science Survey,2019,38(6):71-77. [82] Toms L M L,Mortimer M,Symons R K,et al.Polybrominated diphenyl ethers (PBDEs) in sediment by salinity and land-use type from Australia[J].Environment International,2008,34(1):58-66. [83] 王国庆,许学慧,李跃进.多溴联苯醚及其衍生物在土壤中的分布、转化和生物效应研究进展[J].环境科学研究,2021,34(3):755-765. Wang G Q,Xu X H,Li Y J.Distribution,transformation and biological effects of polybrominated diphenyl ethers and their derivatives in soil:a review[J].Research of Environmental Sciences,2021,34(3):755-765. [84] 陈雷,戴玙芽,陈晓婷,等.全氟及多氟化合物在土壤中的污染现状及环境行为研究进展[J].农业环境科学学报,2021,40(8):1611-1622. Chen L,Dai Y Y,Chen X T,et al.Research progress on the pollution status and environmental behavior of per-and polyfluoroalkyl substances in soil[J].Journal of Agro-Environment Science,2021,40(8):1611-1622. [85] Ukalska-Jaruga A,Smreczak B.The impact of organic matter on polycyclic aromatic hydrocarbon (PAH) availability and persistence in soils[J].Molecules,2020,25(11):2470. [86] Kobližková M,Růžičková P,Čupr P,et al.Soil burdens of persistent organic pollutants:their levels,fate,and risks.Part IV.Quantification of volatilization fluxes of organochlorine pesticides and polychlorinated biphenyls from contaminated soil surfaces[J].Environmental Science & Technology,2009,43(10):3588-3595. [87] 张兆鑫,李家科,蒋春博.土壤典型持久性有机污染物界面行为及调控技术研究进展[J].应用基础与工程科学学报,2021,29(3):517-532. Zhang Z X,Li J Z,Jiang C B.Advances in interfacial behavior and regulation technology of typical persistent organic pollutants in soil[J].Journal of Basic Science and Engineering,2021,29(3):517-532. [88] 高玉娟,谢承劼,余红,等.溴代阻燃剂在土壤中的迁移转化研究进展[J].环境科学研究,2021,34(2):479-490. Gao Y J,Xie C J,Yu H,et al.Research progress on migration and transformation of brominated flame retardants in soil[J].Research of Environmental Sciences,2021,34(2):479-490. [89] 阮哲璞,徐希辉,陈凯,等.微生物降解持久性有机污染物的研究进展与展望[J].微生物学报,2020,60(12):2763-2784. Ruan Z P,Xu X H,Chen K,et al.Recent advances in microbial catabolism of persistent organic pollutants[J].Acta Microbiologica Sinica,2020,60(12):2763-2784. [90] 肖子冰,邢航,窦增培,等.自然环境中能否出现可有效降解碳氟链的微生物[J].日用化学工业,2021,51(12):1242-1249. Xiao Z B,Xing H,Dou Z P,et al.Analysis about whether microorganisms that can effectively degrade fluorocarbon chains would appear in the natural environment[J].China Surfactant Detergent & Cosmetics,2021,51(12):1242-1249. [91] 杨丽芝,杨雪柯,刘春华.山东平原地区浅层地下水有机污染特征分析[J].中国地质调查,2015,2(8):25-30. Yang L Z,Yang X K,Liu C H.Characteristics of organic pollution of shallow groundwater in the Shandong Plain[J].Geological Survey of China,2015,2(8):25-30. [92] 李晨洋,刘爽,孙楠,等.土壤和沉积物中PAHs环境行为研究进展[J].东北农业大学学报,2021,52(3):87-94. Li C Y,Liu S,Sun N,et al.Research progress of PAHs environmental behaviors on soil and sediment[J].Journal of Northeast Agricultural University,2021,52(3):87-94. [93] Nizzetto L,Liu X,Zhang G,et al.Accumulation kinetics and equilibrium partitioning coefficients for semivolatile organic pollutants in forest litter[J].Environmental Science & Technology,2014,48(1):420-428. [94] Kalisa E,Nagato E,Bizuru E,et al.Pollution characteristics and risk assessment of ambient PM2.5-bound PAHs and NPAHs in typical Japanese and New Zealand cities and rural sites[J].Atmospheric Pollution Research,2019,10(5):1396-1403. [95] 穆熙,李尧捷,曹红梅,等.中国西部某规模化电子垃圾拆解厂多氯联苯排放污染特征及职业呼吸暴露风险[J].环境科学学报,2019,39(8):2800-2810. Mu X,Li Y J,Cao H M,et al.Pollution characteristics and occupational inhalation exposure risks of PCBs in a formal and scaled e-waste dismantling plant,western China[J].Acta Scientiae Circumstantiae,2019,39(8):2800-2810. [96] Li Y F,Qiao L N,Ren N Q,et al.Decabrominated diphenyl ethers (BDE-209) in Chinese and global air:levels,gas/particle partitioning,and long-range transport:is long-range transport of BDE-209 really governed by the movement of particles?[J].Environmental Science & Technology,2017,51(2):1035-1042. [97] 冯新斌,曹晓斌,付学吾,等.环境地球化学研究近十年若干新进展[J].矿物岩石地球化学通报,2021,40(2):253-289. Feng X B,Cao X B,Fu X W,et al.Some progresses in environmental geochemistry study in China in the past decade[J].Bulletin of Mineralogy,Petrology and Geochemistry,2021,40(2):253-289. [98] Wang X P,Wang C F,Zhu T T,et al.Persistent organic pollutants in the polar regions and the Tibetan Plateau:a review of current knowledge and future prospects[J].Environmental Pollution,2019,248:191-208. [99] Tian C G,Ma J M,Liu L Y,et al.A modeling assessment of association between East Asian summer monsoon and fate/outflow of α-HCH in Northeast Asia[J].Atmospheric Environment,2009,43(25):3891-3901. [100] Wang X P,Sun D C,Yao T D.Climate change and global cycling of persistent organic pollutants:a critical review[J].Science China Earth Sciences,2016,59(10):1899-1911. [101] Wöhrnschimmel H,Macleod M,Hungerbuhler K.Emissions,fate and transport of persistent organic pollutants to the Arctic in a changing global climate[J].Environmental Science & Technology,2013,47(5):2323-2330. [102] Lei Y D,Wania F.Is rain or snow a more efficient scavenger of organic chemicals?[J].Atmospheric Environment,2004,38(22):3557-3571.