Application and enlightenment of the geochemical exploration in Zaozigou gold deposit
YAN Kang1,2, TANG Yuanhe1,2, GUO Wendi1,2, ZHANG Rui1,2, LI Kangning3, XU Yongli3
1. Xi’an Center of Mineral Resources Survey, China Geological Survey, Shaanxi Xi’an 710100,China; 2. Technology Innovation Center for Gold Ore Exploration, China Geological Survey , Shaanxi Xi’an 710100, China; 3. The Third Geological and Mineral Exploration Institute of Gansu Bureau of Geology and Mineral Resources, Gansu Lanzhou 730050, China
Abstract:Zaozigou gold deposit is located in the northwest of West Qinling orogenic belt, with well-developed vegetation and poor bedrock outcropping. The geochemical exploration is one of the most effective exploration methods in the region. On the basis of systematically combing the geochemical characteristics of 1:200,000 and 1:50,000 water sediment measurements and 1:10,000 soil measurements of Zaozigou gold deposit, the authors found that Au has a positive correlation with Sb, As, Hg, Ag and Cu, combined with the characteristics of the primary halo of the deep borehole SK8314. Especially, the combination of Au and Sb is a direct geochemical marker for gold prospecting. The deep primary halo zoning sequence is Bi-Cu-Mo-Sb-Ag-Au-W-As-Sn-Zn-Cd-Pb-Cr-Ni-Co-Hg, and Bi is located in the leading halo of the zoning sequence. Cu is located in the leading halo of the zoning sequence, and Pb and Zn are located in the tail halo of the zoning sequence, indicating that the ore body has the characteristics of multi-stage metallogenic superposition, probably with blind ore body in the depth. At the same time, the ratios of geochemical parameters (As+Sb)/(Bi+Mo) and 100·Sb/(Bi·Mo) gradually increased with the increasing depth at hole SK8314 below 1 850 m, indicating blind ore bodies in the deeper part and a large prospecting space. The research results could provide some references for deep and peripheral prospecting in Zaozigou.
[1] 杜宛鸽,严康,高永宝,等.西秦岭花崖沟一带金矿找矿新进展[J].中国地质调查,2024,11(1):9-15. Du W G,Yan K,Gao Y B,et al.New progress of gold mineral prospecting in Huayagou area of West Qinling[J].Geological Survey of China,2024,11(1):9-15. [2] 刘彦良,高雅,罗维斌,等.西秦岭温泉-中川一带金属矿床的成矿规律及找矿预测[J].中国地质调查,2018,5(4):40-49. Liu Y L,Gao Y,Luo W B,et al.Metallogenic regularity and prospect prediction of metallic deposits in Wenquan-Zhongchuan area of western Qinling[J].Geological Survey of China,2018,5(4):40-49. [3] 李康宁,贾儒雅,李鸿睿,等.西秦岭早子沟金矿黑云母成分特征及成岩成矿指示意义[J].岩石矿物学杂志,2022,41(5):865-879. Li K N,Jia R Y,Li H R,et al.Composition characteristics of biotite and its implications for diagenesis and mineralization in Zaozigou gold deposit,western Qinling[J].Acta Petrologica et Mineralogica,2022,41(5):865-879. [4] 第鹏飞. 西秦岭夏河-合作早子沟金矿床地球化学特征及成矿机制研究[D].兰州:兰州大学,2018. Di P F.Geochemistry and Ore-Forming Mechanism on Zaozigou Gold Deposit in Xiahe-Hezuo,West Qinling,China[D].Lanzhou:Lanzhou University,2018. [5] 王涛. 甘肃夏河—合作矿集区早子沟金矿成矿作用与找矿预测地质模型研究[D].北京:中国地质大学(北京),2018. Wang T.Research on Mineralization and Geological Model of Prospecting and Prediction of the Zaozigou Gold Deposit in the Xiahe-Hezuo Ore Concentration Area,Gansu Province,China[D].Beijing:China University of Geosciences (Beijing),2018. [6] 梁志录,陈国忠,麻红顺,等.西秦岭早子沟金矿控矿断裂形成演化[J].大地构造与成矿学,2016,40(2):354-366. Liang Z L,Chen G Z,Ma H S,et al.Evolution of ore-controlling faults in the Zaozigou gold deposit,western Qinling[J].Geotectonica et Metallogenia,2016,40(2):354-366. [7] 刘春先,陈耀宇,雒晓刚,等.甘肃合作早子沟特大型金矿床主矿带、主矿体特征及勘查、研究意义剖析[J].矿产与地质,2018,32(6):969-977. Liu C X,Chen Y Y,Luo X G,et al.Study on characteristics and exploration significance of main ore belt and orebody of Zaozigou super large gold deposit in Hezuo,Gansu[J].Mineral Resources and Geology,2018,32(6):969-977. [8] 陈国忠,梁志录,王建龙,等.甘肃合作早子沟金矿原生叠加晕特征及深部预测[J].物探与化探,2014,38(2):268-277. Chen G Z,Liang Z L,Wang J L,et al.Characteristics and deep prediction of primary superimposed halos in the Zaozigou gold deposit of Hezuo,Gansu Province[J].Geophysical and Geochemical Exploration,2014,38(2):268-277. [9] 林成贵,程志中,吕志成,等.甘肃省早子沟金矿原生晕分带特征及深部找矿预测[J].吉林大学学报(地球科学版),2020,50(1):70-84. Lin C G,Cheng Z Z,Lü Z C,et al.Characteristics of primary halo zonation and deep ore prediction in Zaozigou gold deposit,Gansu Province[J].Journal of Jilin University:Earth Science Edition,2020,50(1):70-84. [10] 李康宁,贾儒雅,李鸿睿,等.西秦岭甘肃夏河-合作地区与中酸性侵入岩有关的金铜多金属成矿系统及找矿预测[J].地质通报,2020,39(8):1191-1203. Li K N,Jia R Y,Li H R,et al.The Au-Cu polymetallic mineralization system related to intermediate to felsic intrusive rocks and the prospecting prediction in Xiahe-Hezuo area of Gansu,West Qinling orogenic belt[J].Geological Bulletin of China,2020,39(8):1191-1203. [11] 柳生祥,陈耀宇,刘强,等.甘肃夏河—合作金矿密集区控矿因素及资源潜力分析[J].矿床地质,2012,31(S1):757-758. Liu S X,Chen Y Y,Liu Q,et al.Ore-controlling factors and ore-controlling factors in Xiahe-Hezuo gold deposit intensive area,Gansu resource potential analysis[J].Mineral Deposits,2012,31(S1):757-758. [12] 严康,韦乐乐,张建鹏,等.甘肃省根沙塘地区地球化学、地球物理特征及找矿模型[J].黄金,2020,41(8):8-12,30. Yan K,Wei L L,Zhang J P,et al.Geochemical and geophysical characteristics and prospecting model of Genshatang area,Gansu Province[J].Gold,2020,41(8):8-12,30. [13] 秦江锋. 秦岭造山带晚三叠世花岗岩类成因机制及深部动力学背景[D].西安:西北大学,2010. Qin J F.Petrogenesis and Geodynamic Implications of the Late-Triassic Granitoids from the Qinling Orogenic Belt[D].Xi’an:Northwest University.2010. [14] 刘伯崇,李康宁,史海龙,等.西秦岭甘青交界一带晚三叠世火山岩岩石成因及构造指示意义[J].现代地质,2018,32(4):704-717. Liu B C,Li K N,Shi H L,et al.Petrogenesis and tectonic implications of late triassic volcanic rocks at the Gansu-Qinghai junction in the West Qinling mountains[J].Geoscience,2018,32(4):704-717. [15] 王忠良. 合作幅I-48-(7)地区化学图说明书[R].甘肃省地质矿产局地球化学探矿队,1988. Wang Z L.Cooperation i-48-(7) Regional Chemical Diagram Description[R].Geochemical Prospecting Team of Gansu Provincial Bureau of Geology and Mineral Resources,1988. [16] 齐建宏,李注苍,杨志勇,等.甘肃省合作-美武一带1:5万矿产远景调查报告[R].甘肃省地质矿产勘查开发局第三地质矿产勘查院,2022. Qi J H,Li Z C,Yang Z Y,et al.Gansu Province Cooperation-Meiwu Area 1:50,000 Mineral Prospect Survey Report[R].The Third Geological and Mineral Exploration Institute of Gansu Bureau of Geology and Mineral Resources,2022. [17] 李康宁,程志中,李鸿睿,等.西秦岭早子沟金矿中酸性侵入岩地球化学、年代学特征及成矿地质体的确定[J].岩石矿物学杂志,2023,42(2):205-219. Li K N,Cheng Z Z,Li H R,et al.Geochemical and chronological characteristics of intermediate-acid intrusive rocks in Zaozigou gold deposit,western Qinling,and the determination of metallogenic geological body[J].Acta Petrologica et Mineralogica,2023,42(2):205-219. [18] 李康宁,李鸿睿,贾儒雅,等.甘肃早子沟金矿“三位一体”找矿预测地质模型的构建[J].矿产勘查,2019,10(6):1397-1408. Li K N,Li H R,Jia R Y,et al.Construction of the geological model of “trinity” prospecting prediction in Zaozigou gold deposit,Gansu Province[J].Mineral Exploration,2019,10(6):1397-1408. [19] 陈国忠,梁志录,麻红顺,等.甘肃省合作市早子沟金矿床地质模型的建立及资源总量估算[J].西北地质,2013,46(4):173-181. Chen G Z,Liang Z L,Ma H S,et al.The establishment of geological model and totalresources estimate of the Zaozigou gold deposit,Hezuo,Gansu Province[J].Northwestern Geology,2013,46(4):173-181. [20] 陈国忠,李康宁,张愿宁,等.早子沟金矿流体包裹体特征及矿床成因[J].吉林大学学报(地球科学版),2015,45(S1):1-2. Chen G Z,Li K N,Zhang Y N,et al.Characteristics of fluid inclusions and genesis of Zaozigou gold deposit[J].Journal of Jilin University:Earth Science Edition,2015,45(S1):1-2. [21] 李康宁,李鸿睿,严康,等.甘肃省玛曲—合作整装勘查区深部找矿预测与钻探工程项目成果报告[R].甘肃省地质矿产勘查开发局第三地质矿产勘查院,2020. Li K N,Li H R,Yan K,et al.Gansu Province Maqu-Cooperative Integrated Exploration Area Deep Prospecting Prediction and Drilling Project Results Report[R].The Third Geological and Mineral Exploration Institute of Gansu Bureau of Geology and Mineral Resources,2020. [22] DZ/T 0011—2015 Specification of geochemical reconnaissance survey (1:50 000)[S]. DZ/T 0011—2015 Specification of geochemical reconnaissance survey (1:50 000)[S]. [23] DZ/T 0130.4—006 地质矿产实验室测试质量管理规范 第4部分:区域地球化学调查(1:50 000和1:200 000)样品化学成分分析[S]. DZ/T 0130.4—2006 The specification of testing quality management for geological laboratories:Part 4:chemical component analysis of regional geochemical samples (for 1:50,000 and 1:200,000 geochemical mapping)[S]. [24] 刘崇民,马生明,胡树起.金属矿床原生晕勘查指标[J].物探与化探,2010,34(6):765-771. Liu C M,Ma S M,Hu S Q.A study of primary halo exploration indexes for metallic ore deposits[J].Geophysical and Geochemical Exploration,2010,34(6):765-771. [25] 李惠,禹斌,李德亮,等.化探深部预测新方法综述[J].矿产勘查,2010,1(2):156-160. Li H,Yu B,Li D L,et al.Summary of new methods on deep prediction of geochemical exploration[J].Mineral Exploration,2010,1(2):156-160. [26] 李惠,张国义,禹斌,等.构造叠加晕找盲矿法及其在矿山深部找矿效果[J].地学前缘,2010,17(1):287-293. Li H,Zhang G Y,Yu B,et al.Structural superimposed halos method for prospecting blind ore-body in the deep of ore-districts[J].Earth Science Frontiers,2010,17(1):287-293. [27] 严康,王滔,韦乐乐,等.甘肃大水金矿原生晕特征及深部矿体预测[J].矿产勘查,2019,10(6):1444-1452. Yan K,Wang T,Wei L L,et al.Primary halo feature and deep orebody prediction of Dashui gold deposit in Gansu province[J].Mineral Exploration,2019,10(6):1444-1452. [28] 李惠,张文华,刘宝林,等.金矿床轴向地球化学参数叠加结构的理想模式及其应用准则[J].地质与勘探,1999,35(6):41-44. Li H,Zhang W H,Liu B L,et al.Ideal model and principle of staching structure of axial geochemical parameter of gold deposit[J].Geology and Exploration,1999,35(6):41-44.