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Geochemical characteristics and palaeoenvironmental significance of the paleo-weathered crust at the Carboniferous bottom in Wudang of Guiyang |
ZHANG Yingshuai, MAO Jiaren, WANG Qilin, XIAO Yu, WANG Ganlu |
Resources and Environmental Engineering College, Guizhou University, Guiyang 550025, China |
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Abstract A well-preserved paleo-weathered crust of carbonate rocks is found at the bottom of Carboniferous Xiangbai Formation at Xiaoguankou Section of Wudang, Guiyang. Based on field observation and indoor comprehensive research, it can be referred that the paleo-weathered crust is mainly composed of grey-green or brick-red ferrous kaolinite claystone and limonite-bearing silty claystone. Al2O3, TiO2 and Fe2O3 as the major elements are rich in the paleo-weathered crust. SiO2 is leached slightly, but K2O, Na2O, CaO and MgO are leached seriously. Trace elements, including Sc, V, Cr, Cu, Zn, Ga, Ba, Th and Pb, are relatively enriched, and Sr, Mn as the soluble elements are leached. The indexes, including Sr/Cu, A/NK, A/CNK, OI and CIA, all indicate that the paleo-weathered crust should be formed under the tropical to subtropical paleoclimate conditions of strong weathering, torridity and humidity. In addition, due to the stability of the paleo-weathered crust and the lithological characteristics of parent-rock, the authors inferred that ancient karst landform including karst depression and highland had been widely developed during the formation of paleo-weathered crust.
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Received: 22 August 2017
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